Polymerization Reactions in Solid State

Some Aspects of Solid State Polymerization

Previous investigations on solid state polymerization are reviewed, and a few examples of new experimental results are added. Radiation-induced polymerizations of methyl methacrylate in the supercooled liquid phase, and of cyclohexene oxide in the plastic crystalline phase, have been examined. Polymerizations of acrylamide and N-vinylcarbazole were investigated on a solid surface with initiatio...

Functional diversity in templated solid state reactions

Polymerization Reactions

The tremendous growth of polymer production since the middle of the twentieth century has been intimately connected with the development of new types of catalysts, A notable example in this regard is the field of poly olefin materials, While catalysts are also used in the production of other types of polymers, the properties of most of these materials are not particularly dependent on the type ...

Manganese Antimonate: Facile solid state synthesis, characterization and its application for Biginelli reactions

Nanostructured Mn2Sb2O7 powders were synthesized via stoichiometric1:1 Mn:Sb molar ratio solid state reaction at different reactions temperatures for 8 h using MnSO4.H2O and Sb2O3 as raw materials. The synthesized materials were characterized by powder X-ray diffraction (PXRD) technique. Structural analyses were performed by the FullProf program employing profile matching with constant scale fa...

Kinetics of consecutive reactions in the solid state:

The thermal and kinetic aspects of solid state decomposition reactions can be complex and posses a large number of parameters to investigate. The determination of the activation energies for the several intermediates in the thermal decomposition is particularly sensitive to the overlap in thermal decomposition traces. To overcome this problem we have undertaken the detailed kinetic analysis of ...